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This article examines the influence of mentorship on women entrepreneurs in Cape Town, South Africa. The study assesses the extent to which mentorship contributes to personal empowerment, entrepreneurial performance, and innovation, while accounting for the effects of systemic barriers and the policy environment. A qualitative research design was employed, incorporating a systematic literature review guided by the preferred reporting items for systematic reviews and Meta-Analyses (PRISMA) framework to synthesize existing evidence. The review followed an iterative screening process, identifying three peer-reviewed studies that explicitly address mentorship in relation to women entrepreneurs within the African context. The findings from the literature indicate that women entrepreneurs across Africa face persistent structural constraints, including social-cultural norms, limited access to skills development, weak support systems, financial exclusion, and inadequate policy frameworks.  To complement the literature, primary data were collected from ten young female entrepreneurs in Cape Town who participated in a mentorship programme at RLabs. The empirical finding reinforce the significance of mentorship as a critical enabler of entrepreneurial growth, particularly in enhancing self-efficacy, business capabilities, and innovative practices. The study concludes that mentorship functions as a context-dependent and multifaceted mechanism that bridges personal empowerment and entrepreneurial outcomes. However, its effectiveness is contingent on the alignment of mentorship programmes with the specific social-economic realities of women entrepreneurs. The article recommends the design and implementation of targeted, context-sensitive mentorship interventions supported by enabling policy frameworks. While women's entrepreneurship is increasingly recognised as a catalyst for economic development in Africa, persistent systemic constraints continue to impede their full potential. This study contributes to literature by advancing a nuanced understanding of mentorship as both an individual and structural lever for entrepreneurial success within emerging economies.